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Divergence
The divergence of a vector field measures its local tendency to produce net outward flow. Rather than being an arbitrary combination of derivatives, its formula comes from comparing what a field carries into and out of a tiny region.
For
$$\mathbf F=(P,Q,R),$$
consider a small rectangular box with side lengths $\Delta x$, $\Delta y$, and $\Delta z$.
Why $\partial P/\partial x$ appears
On the two faces perpendicular to the $x$-axis, only the $x$-component $P$ contributes to outward flow. The contribution from the right face minus the contribution entering through the left face is approximately
$$\bigl(P(x+\Delta x,y,z)-P(x,y,z)\bigr),\Delta y,\Delta z.$$
For a sufficiently small box,
$$P(x+\Delta x,y,z)-P(x,y,z) \approx \frac{\partial P}{\partial x},\Delta x,$$
so the net $x$-contribution is approximately
$$\frac{\partial P}{\partial x},\Delta x,\Delta y,\Delta z.$$
The same reasoning in the other two directions gives
$$\frac{\partial Q}{\partial y},\Delta x,\Delta y,\Delta z$$
and
$$\frac{\partial R}{\partial z},\Delta x,\Delta y,\Delta z.$$
Adding the three contributions and dividing by the box volume leaves
$$\boxed{\nabla\cdot\mathbf F
\frac{\partial P}{\partial x} + \frac{\partial Q}{\partial y} + \frac{\partial R}{\partial z}}.$$
Divergence is therefore the net outward tendency per unit volume in the infinitesimal limit.
Sources, sinks, and zero divergence
If $\nabla\cdot\mathbf F>0$, a tiny region around the point has more outward than inward flow to first order, so the point behaves locally like a source. If $\nabla\cdot\mathbf F<0$, it behaves like a sink.
Zero divergence does not mean that the field is zero or even constant. It means only that there is no first-order net expansion or compression there.
Examples
For the radial field
$$\mathbf F(x,y,z)=(x,y,z),$$
we obtain
$$\nabla\cdot\mathbf F=1+1+1=3.$$
Every small box has positive net outward tendency, matching the picture of arrows spreading away from the origin.
By contrast, for
$$\mathbf F(x,y,z)=(-y,x,0),$$
$$\nabla\cdot\mathbf F=0+0+0=0.$$
The field circulates around the $z$-axis without locally expanding or contracting volume.
Divergence is a local quantity. The divergence theorem later shows that accumulating this local source strength throughout a volume gives the total outward flux through its boundary.