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Matrix addition and scalar multiplication
Matrices of the same dimensions can be added entry by entry. If $A$ and $B$ are both $m\times n$, then
$$(A+B){ij}=A{ij}+B_{ij}.$$
For example,
$$\begin{pmatrix}1&2\3&4\end{pmatrix} + \begin{pmatrix}5&-1\0&2\end{pmatrix}
\begin{pmatrix}6&1\3&6\end{pmatrix}.$$
Matrices with different dimensions cannot be added because their entries do not line up.
Scalar multiplication
Multiplying a matrix by a scalar multiplies every entry:
$$cA=(cA_{ij}).$$
For example,
$$2\begin{pmatrix}1&-3\4&0\end{pmatrix}
\begin{pmatrix}2&-6\8&0\end{pmatrix}.$$
Linear structure
These operations follow the same patterns as vector addition and scalar multiplication. For example,
$$A+B=B+A,$$
$$c(A+B)=cA+cB.$$
This shared linear structure is one reason matrices and vectors fit naturally into the same theory.