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Calculating eigenvalues and eigenvectors
For a matrix $A$, an eigenvector satisfies
$$A\mathbf v=\lambda\mathbf v.$$
Rearranging gives
$$(A-\lambda I)\mathbf v=\mathbf0.$$
A nonzero solution exists only when $A-\lambda I$ is not invertible. Therefore its determinant must vanish.
The characteristic equation
Eigenvalues are found from
$$\det(A-\lambda I)=0.$$
The expression
$$p_A(\lambda)=\det(A-\lambda I)$$
is the characteristic polynomial.
For example, if
$$A=\begin{pmatrix}2&0\0&3\end{pmatrix},$$
then
$$\det(A-\lambda I)=(2-\lambda)(3-\lambda),$$
so the eigenvalues are $2$ and $3$.
Finding eigenvectors
For each eigenvalue, solve
$$(A-\lambda I)\mathbf v=\mathbf0.$$
For $\lambda=2$ in the example,
$$A-2I=\begin{pmatrix}0&0\0&1\end{pmatrix},$$
so $v_2=0$ and $v_1$ is free. The eigenspace is therefore
$$\operatorname{span}((1,0)).$$
Similarly, the eigenspace for $\lambda=3$ is $\operatorname{span}((0,1)).$$
Multiplicity
An eigenvalue may occur more than once as a root of the characteristic polynomial. This is its algebraic multiplicity.
The dimension of its eigenspace is its geometric multiplicity. The geometric multiplicity is at least $1$ and cannot exceed the algebraic multiplicity.
Calculating eigenvectors therefore combines determinant equations with homogeneous linear systems.