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Intensive, extensive and specific thermodynamic properties

Thermodynamic properties differ in how they scale with system size.

An extensive property scales with the amount of matter. If two identical systems are combined, their mass $m$ and volume $V$ double.

An intensive property does not scale with system size. Temperature $T$, pressure $p$ and density $\rho$ remain the same when two identical equilibrium systems are combined.

Dividing an extensive property by mass produces a specific property. The most immediate example is specific volume:

$$v=\frac{V}{m}.$$

Because density is $\rho=m/V$,

$$v=\frac{1}{\rho}.$$

For example, if $2\ \mathrm{kg}$ of a substance occupies $0.50\ \mathrm{m^3}$, then

$$v=\frac{0.50}{2}=0.25\ \mathrm{m^3/kg},\qquad \rho=4\ \mathrm{kg/m^3}.$$

The same construction can be applied to other extensive properties once they are introduced. Specific properties let thermodynamic relations describe systems independently of their total mass.