Unit content
Lewis structures and the octet model
A Lewis structure allocates valence electrons among covalent bonds and lone pairs. It is a bookkeeping model for connectivity and valence electron distribution, not a literal picture of a molecule's three-dimensional shape.
For many main-group molecules, a useful first model is the octet rule: atoms tend to appear in structures with eight valence-shell electrons around them. Hydrogen is an important exception because its first shell is filled by two electrons.
To construct a simple Lewis structure:
- Count all available valence electrons, adding electrons for negative charge and subtracting them for positive charge.
- Choose a plausible connectivity and join bonded atoms with single bonds. Each bond uses two electrons.
- Complete the valence shells of terminal atoms.
- Place remaining electrons on the central atom.
- If the central atom still lacks an octet, convert suitable neighboring lone pairs into multiple bonds.
For $CO_2$, the total is $4+2(6)=16$ valence electrons. Starting from $O-C-O$, completing both oxygen octets leaves carbon electron-deficient. Converting one lone pair from each oxygen into a bond gives
O=C=O
with two lone pairs on each oxygen and an octet around every atom.
The octet model is highly useful but not universal. Electron-deficient, odd-electron and expanded-valence species require explicit treatment beyond this basic construction method.