Unit content
The electron-volt as an energy unit
Atomic, molecular, semiconductor, nuclear, and particle energies are often far smaller than one joule. A convenient unit for these scales is the electron-volt.
One electron-volt is the energy corresponding to one elementary charge multiplied by one volt:
$$\boxed{1,\mathrm{eV}=e,(1,\mathrm V)}.$$
Since
$$e=1.602176634\times10^{-19},\mathrm C$$
and
$$1,\mathrm V=1,\mathrm{J/C},$$
$$\boxed{1,\mathrm{eV}=1.602176634\times10^{-19},\mathrm J}.$$
This conversion is exact in the modern SI.
Electron-volts measure energy, not voltage
Despite its name, the electron-volt is a unit of energy. The volt is a different quantity: one volt is one joule per coulomb.
The name comes from electrostatics: a particle with charge magnitude $e$ changes its electric potential energy by one electron-volt when it moves through a potential difference of one volt in the appropriate direction. But once defined, the electron-volt can be used for any kind of energy, including photon energies, binding energies, band gaps, and particle rest energies.
Converting between electron-volts and joules
To convert electron-volts to joules, multiply by
$$1.602176634\times10^{-19},\mathrm{J/eV}.$$
For example,
$$500,\mathrm{eV} =(500)(1.602176634\times10^{-19}),\mathrm J \approx8.01\times10^{-17},\mathrm J.$$
To convert joules to electron-volts, divide by the same factor. For example,
$$3.204\times10^{-19},\mathrm J \approx2.00,\mathrm{eV}.$$
Common multiples
Useful multiples include
$$1,\mathrm{keV}=10^3,\mathrm{eV},$$
$$1,\mathrm{MeV}=10^6,\mathrm{eV},$$
$$1,\mathrm{GeV}=10^9,\mathrm{eV}.$$
Thus
$$1,\mathrm{MeV}=1.602176634\times10^{-13},\mathrm J.$$
Electron-volts do not introduce a new kind of energy. They simply provide a convenient unit for microscopic energy scales.