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Variance and standard deviation
Expected value describes the center of a distribution, but two distributions with the same mean can have very different amounts of spread. Variance measures how far values typically lie from the mean by averaging squared deviations.
If $\mu=E[X]$, then
$$\operatorname{Var}(X)=E[(X-\mu)^2].$$
Why the deviations are squared
The ordinary deviations $X-\mu$ have mean zero, because positive and negative deviations cancel. Squaring makes all contributions nonnegative and gives larger deviations more weight.
An equivalent formula is
$$\operatorname{Var}(X)=E[X^2]-E[X]^2.$$
For calculations this form is often simpler.
Standard deviation
Variance is measured in squared units. The standard deviation returns to the original units of $X$:
$$\sigma_X=\sqrt{\operatorname{Var}(X)}.$$
A small standard deviation means values are concentrated near the mean; a large one means the distribution is more spread out.
Shifting and scaling
Adding a constant changes the center but not the spread:
$$\operatorname{Var}(X+b)=\operatorname{Var}(X).$$
Multiplying by $a$ scales deviations by $a$, so
$$\operatorname{Var}(aX)=a^2\operatorname{Var}(X),$$
and therefore
$$\operatorname{SD}(aX)=|a|\operatorname{SD}(X).$$
Variance and standard deviation describe spread around the expected value, not the full shape of the distribution.